Fabrication of [60] Fullerene Grafted Polymer: Self-Assembly Behavior in Polar Solvents

Title
Fabrication of [60] Fullerene Grafted Polymer: Self-Assembly Behavior in Polar Solvents
Author(s)
할도리유바라즈심재진나오샤드이슬람
Keywords
HYDROPHOBIC INTERACTIONS; INTERPOLYMER COMPLEXES; AGGREGATION BEHAVIOR; ACID) COMPLEXES; COPOLYMERS; C-60; METHACRYLATE; CHEMISTRY; STYRENE
Issue Date
201401
Publisher
ASIAN JOURNAL OF CHEMISTRY
Citation
ASIAN JOURNAL OF CHEMISTRY, v.26, no.2, pp.617 - 620
Abstract
In of this report we prepared anew type of [60] fullerene grafted poly(2-bromomethyl)acrylic acid. First step was the free-radical polymerization of 2-(bromomethyl)acrylic acid Wing 2,2'-azobisisobutyronitrile. Then:a nucleophilie substitution reaction was performed to substitute the bromine atoms present in the polymer with azide groups Finally the C-60 grafted polymer was prepared by the reaction of azido functionalized polymer with C-60. Results of Fourier transform infrared spectroscopy and ultraviolet visible spectroscopy indicated that the C-60 was Chemically bonded to the polymer, The aggregation behavior of the resulting polymer in polar solvents was studied by transmission electron microscopy. The resultant polymer retained both electronic property of the C-60 moiety and processability property of the polymer.
URI
http://hdl.handle.net/YU.REPOSITORY/33475
ISSN
0970-7077
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공과대학 > 화학공학부 > Articles
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