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dc.contributor.author요네스피로즈살라리ko
dc.contributor.authorBabak Mirtamizdoust[Babak Mirtamizdoust]ko
dc.contributor.authorAli Morsali[Ali Morsali]ko
dc.contributor.author주상우ko
dc.date.accessioned2015-12-17T05:00:08Z-
dc.date.available2015-12-17T05:00:08Z-
dc.date.created2015-11-13-
dc.date.issued201503-
dc.identifier.citationULTRASONICS SONOCHEMISTRY, v.23, pp.275 - 281-
dc.identifier.issn1350-4177-
dc.identifier.urihttp://hdl.handle.net/YU.REPOSITORY/33162-
dc.identifier.urihttp://dx.doi.org/10.1016/j.ultsonch.2014.10.022-
dc.description.abstractThe new neutral binuclear lead(II) azido coordination compound, [Pb-2(tmph)(2)(mu-N-3)(2)(CH3COO)(2)] (1) [tmph = 3,4,7,8-tetramethyl-1,10-phenanthroline], has been synthesized by a sonochemical method. Single crystal X-ray structure shows that the overall structure of 1 is binuclear unit. Complex 1 has a bridging azido pathway, end-to-end bridging azides between a pair of lead(II) centers. This is further extended into a one-dimensional (1D) and three-dimensional (3D) supramolecular structure by Pb center dot center dot center dot C and pi-pi weak directional intermolecular interactions. The coordination number of lead(II) ions is seven, PbN4O3, with two N-donor atoms from tmph ligands and three O-donors from acetate anions and two N-donors from two azide anions. It has a "stereo-chemically active" electron lone pair, and the coordination sphere is hemidirected. The PbO nanoparticles were obtained by thermolysis of 1 at 180 degrees C with oleic acid as a surfactant. The morphology and size of the prepared PbO samples were further observed using scanning electron microscopy (SEM). (C) 2014 Elsevier B.V. All rights reserved.-
dc.language영어-
dc.publisherELSEVIER SCIENCE BV-
dc.subjectMETAL-ORGANIC FRAMEWORKS-
dc.subjectCOORDINATION POLYMERS-
dc.subjectCRYSTAL-STRUCTURE-
dc.subjectCOMPLEXES-
dc.subjectPHEN=1,10-PHENANTHROLINE-
dc.subjectMECHANOSYNTHESIS-
dc.subjectSERIES-
dc.titleSonochemical syntheses of binuclear lead(II)-azido supramolecule with ligand 3,4,7,8-tetramethyl-1,10-phenanthroline as precursor for preparation of lead(II) oxide nanoparticles-
dc.typeArticle-
dc.identifier.wosid000347023100036-
dc.identifier.scopusid2-s2.0-84911870347-
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중앙도서관 > rims journal
공과대학 > 기계공학부 > Articles
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