Characterization of Ni and W co-loaded SBA-15 catalyst and its hydrogen production catalytic ability on ethanol steam reforming reaction

Title
Characterization of Ni and W co-loaded SBA-15 catalyst and its hydrogen production catalytic ability on ethanol steam reforming reaction
Author(s)
강미숙김동진곽병섭민봉기
Keywords
PERFORMANCE; ADSORPTION; COMBUSTION
Issue Date
201503
Publisher
ELSEVIER SCIENCE BV
Citation
APPLIED SURFACE SCIENCE, v.332, pp.736 - 746
Abstract
This study evaluated the application of advanced bimetallic catalytic species of Ni and W to effectively produce hydrogen gases from ethanol steam reforming. The highest reactivity was achieved using the Ni(0.95)W(0.05/)SBA-15 catalyst. The maximum H-2 production and ethanol conversion of 90% and 85%, respectively, were obtained for 0.4 g catalyst at 600 degrees C after 10 h with a EtOH:H2O ratio of 1:3 and a gas hourly space velocity of 6000 h(-1). This highlights a synergy between the Ni and W loading on SBA-15 during ethanol steam reforming that occurs through the inhibition of Ni particle agglomeration and consequent decrease in catalytic deactivation. Additionally, the supplied W ingredients promoted CO2 selectivity, which was generated from the CO-water gas shift reaction. (C) 2015 Elsevier B.V. All rights reserved.
URI
http://hdl.handle.net/YU.REPOSITORY/33105http://dx.doi.org/10.1016/j.apsusc.2014.12.180
ISSN
0169-4332
Appears in Collections:
이과대학 > 화학생화학부 > Articles
문과대학 > 중국언어문화학과 > Articles
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