Hydrothermal synthesis of a nano-rod mercury(ii) metal-ligand coordination compound

Title
Hydrothermal synthesis of a nano-rod mercury(ii) metal-ligand coordination compound
Author(s)
주상우요네스피로즈살라리알리레자카타이민봉기
Keywords
CRYSTAL-STRUCTURE; POLYMERS; ANION; ACIDS; THIOCYANATE; MOLECULES; SOLVENT; ADDUCT; MODES
Issue Date
201405
Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
Citation
JOURNAL OF STRUCTURAL CHEMISTRY, v.55, no.3, pp.570 - 575
Abstract
A novel nano-rod mercury(II) coordination compound [Hg (BINH)I-2] (1), (BINH is the abbreviation of benzylideneisonicotinohydrazide) is synthesized by a hydrothermal method that produces the coordination compound at a nanosize level. The new nanostructure is characterized by scanning electron microscopy, powder X-ray diffraction, elemental analysis, and IR spectroscopy. Compound 1 was structurally characterized by single crystal X-ray diffraction and the single-crystal structure of this complex shows that each mercury(II) center is four-coordinated with two N-donor atoms from tow BINH ligands and tow iodo anions. Self-assembly of this complexes is pereformed by CHa <-I and pi-pi stacking interactions. The supramolecular features in these complexes are controlled by weak directional intermolecular interactions.
URI
http://hdl.handle.net/YU.REPOSITORY/32237http://dx.doi.org/10.1134/S0022476614030275
ISSN
0022-4766
Appears in Collections:
공과대학 > 기계공학부 > Articles
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