Facile synthesis and crystal structure of 1,5-dimethyl-6-thioxo-1,3,5-triazinane-2,4-dione

Title
Facile synthesis and crystal structure of 1,5-dimethyl-6-thioxo-1,3,5-triazinane-2,4-dione
Author(s)
주상우N. Shajari[N. Shajari]A.R. Kazemizadeh[A.R. Kazemizadeh]A. Ramazani[A. Ramazani]K. Slepokura[K. Slepokura]T. Lis[T. Lis]A. Souldozi[A. Souldozi]
Keywords
SOLVENT-FREE CONDITIONS; STABILIZED PHOSPHORUS YLIDES; ONE-POT; X-RAY; DERIVATIVES; COUMARINS; ALKYL
Issue Date
201507
Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
Citation
JOURNAL OF STRUCTURAL CHEMISTRY, v.56, no.4, pp.806 - 810
Abstract
The title compound 1,5-dimethyl-6-thioxo-1,3,5-triazinane-2,4-dione C5H7N3O2S is synthesized via the reaction between N,N'-dimethylthiourea and trichloroacetyl isocyanate in dichloromethane. The structure of the title compound is characterized by IR, (HNMR)-H-1, C-13 NMR, elemental analysis, and single-crystal X-ray diffraction. The crystal structure reveals the role of N-H...O and C-H...O hydrogen bonds, and C=O...pi interactions in the arrangement of the molecules into ribbons, which are further joined to each other to form double-layers parallel to the (001) plane.
URI
http://hdl.handle.net/YU.REPOSITORY/31537http://dx.doi.org/10.1134/S0022476615040332
ISSN
0022-4766
Appears in Collections:
공과대학 > 기계공학부 > Articles
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