Unusual Product Distribution from Friedlander Reaction of Di- and Triacetylbenzenes with 3-Aminonaphthalene-2-carbaldehyde and Properties of New Benzo[g]quinoline-Derived Aza-aromatics

Title
Unusual Product Distribution from Friedlander Reaction of Di- and Triacetylbenzenes with 3-Aminonaphthalene-2-carbaldehyde and Properties of New Benzo[g]quinoline-Derived Aza-aromatics
Author(s)
장영동모이눌카림
Keywords
CYCLOMETALATED IRIDIUM(III) COMPLEXES; PHOSPHORESCENT; LIGHT; QUINOLINES; EFFICIENCY; LIGANDS; OLEDS
Issue Date
201408
Publisher
MDPI AG
Citation
MOLECULES, v.19, no.8, pp.12842 - 12851
Abstract
The Friedlander reactions of acetylbenzenes and 2-acetylpyridine with 3-aminonaphthalene-2-carbaldehyde afforded the corresponding 2-phenylbenzo[g]quinoline and 2-(pyrid-2-yl)benzo[g]quinoline, respectively. The same reactions of 3-aminonaphthalene-2-carbaldehyde with 1,2-, 1,3-, 1,4-di- and 1,3,5-triacetylbenzenes, however, afforded a series of corresponding (benzo[g]quinolin-2-yl)benzenes as new N,C-bidentate and unexpected benzo[g]quinoline. Crystallinity, thermal properties, absorption and emission spectral properties of the products were studied.
URI
http://hdl.handle.net/YU.REPOSITORY/31167http://dx.doi.org/10.3390/molecules190812842
ISSN
1420-3049
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약학대학 > 약학부 > Articles
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