A Convenient and Efficient Protocol for the Synthesis of HBIW Catalyzed by Silica Nanoparticles under Ultrasound Irradiation

Title
A Convenient and Efficient Protocol for the Synthesis of HBIW Catalyzed by Silica Nanoparticles under Ultrasound Irradiation
Author(s)
주상우Ramak Arabian[Ramak Arabian]Ali Ramazani[Ali Ramazani]Bita Mohtat[Bita Mohtat]Vahid Azizkhani[Vahid Azizkhani]Morteza Rouhani[Morteza Rouhani]
Keywords
ONE-POT SYNTHESIS; DERIVATIVES; ISOCYANIDES; ALDEHYDES; AMINES
Issue Date
201410
Publisher
TAYLOR & FRANCIS INC
Citation
JOURNAL OF ENERGETIC MATERIALS, v.32, no.4, pp.300 - 305
Abstract
2,4,6,8,10,12-Hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.0(5,9).0(3,11)]dodecane (hexabenzylhexaazaisowurtzitane, HBIW) has been synthesized by the reaction of benzylamine and glyoxal (40% aqueous solution) in acetonitrile as a solvent catalyzed by silica nanoparticles (SiO2 NPs, ca. 42nm) under ultrasound irradiation. The effects of solvent, catalyst, and ultrasonic power are discussed. With optimized reaction conditions, HBIW was synthesized under the influence of ultrasound irradiation. Compared with conventional methods, the remarkable advantages of this method are the simple experimental procedure, shorter reaction time, and high product yield.
URI
http://hdl.handle.net/YU.REPOSITORY/30626http://dx.doi.org/10.1080/07370652.2013.869637
ISSN
0737-0652
Appears in Collections:
공과대학 > 기계공학부 > Articles
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