Synthesis of Diverse Indene Derivatives from 1-Diazonaphthalen-2(1H)-ones via Thermal Cascade Reactions

Title
Synthesis of Diverse Indene Derivatives from 1-Diazonaphthalen-2(1H)-ones via Thermal Cascade Reactions
Author(s)
이용록소마이마가크리쉬나
Keywords
H BOND ACTIVATION; WOLFF REARRANGEMENT; EFFICIENT SYNTHESIS; DIAZODICARBONYL COMPOUNDS; CATALYZED SYNTHESIS; FLASH-PHOTOLYSIS; ACID; CYCLIZATION; CONSTRUCTION; SKELETONS
Issue Date
201309
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.15, no.17, pp.4288 - 4291
Abstract
A sequential Wolff rearrangement of 1-diazonaphthalen-2(1H)-ones followed by trapping of the ketene intermediate with primary and aromatic amines or alcohols and phenols in the presence of various aldehydes generates 1H-indene-3-carboxamides or 1H-indene-3-carboxylates. This constitutes an unprecedented three-component coupling reaction that allows for the synthesis of functionalized indene derivatives under catalyst-free thermal conditions.
URI
http://hdl.handle.net/YU.REPOSITORY/29005http://dx.doi.org/10.1021/ol4019908
ISSN
1523-7060
Appears in Collections:
공과대학 > 화학공학부 > Articles
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