Copper(II) triflate-catalyzed reactions for the synthesis of novel and diverse quinoline carboxylates

Title
Copper(II) triflate-catalyzed reactions for the synthesis of novel and diverse quinoline carboxylates
Author(s)
이용록판딧라메쉬월프라사드
Keywords
FRIEDLANDER SYNTHESIS; POLYSUBSTITUTED QUINOLINES; EFFICIENT SYNTHESIS; CYCLIZATION; MECHANISM; SKRAUP; ACID; DERIVATIVES; INHIBITORS; PYRIDINE
Issue Date
201311
Publisher
ROYAL SOC CHEMISTRY
Citation
RSC ADVANCES, v.3, no.44, pp.22039 - 22045
Abstract
An efficient one-pot synthesis of a variety of quinoline carboxylates was accomplished by Cu(OTf)(2)-catalyzed reactions of Michael addition/cyclization/aromatization between 2-aminoaryl carbonyls and alkynyl carboxylates. This methodology offers several significant advantages, namely, ease of handling, mild reaction conditions, enhanced reaction rates, and use of an effective and non-toxic catalyst. The synthesized compounds were further transformed into highly functionalized novel quinoline carboxylates bearing aromatic rings on the quinoline skeleton using the Suzuki reaction.
URI
http://hdl.handle.net/YU.REPOSITORY/28582http://dx.doi.org/10.1039/c3ra44943b
ISSN
2046-2069
Appears in Collections:
공과대학 > 화학공학부 > Articles
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