Synthesis and Photovoltaic Performance of Ionic Dyes for Quasi-Solid State Dye-Sensitized Solar Cells

Title
Synthesis and Photovoltaic Performance of Ionic Dyes for Quasi-Solid State Dye-Sensitized Solar Cells
Author(s)
정미란한윤수[한윤수]정대영양현식김재홍이도경[이도경]
Keywords
CHARGE-TRANSFER; COMPOSITE ELECTROLYTE; ORGANIC-DYES; CONVERSION; RECOMBINATION; COADSORBENT; EFFICIENT
Issue Date
201312
Publisher
TAYLOR & FRANCIS LTD
Citation
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, v.586, no.1, pp.111 - 120
Abstract
We prepared the ionic dyes and investigated their electrochemical properties and photosensitizing performances in the quasi-solid state dye-sensitized solar cells (QS-DSSCs). The LUMO energy level of ionic dye with carbazole moiety is higher than that of the dyes with phenothiazine and triphenylamine chromophore, resulting in highest power conversion efficiency (PCE) in the QD-DSSC. Compared with Ru-complex sensitizer, the ionic dyes showed relatively low photovoltaic performance in the QS-DSSCs, originating in lower LUMO energy level. The effect of Li(+)ion in the quasi-solid state electrolyte on the photovoltaic characteristics of QS-DSSCs was investigated in order to confirm the correlation between the conduction band of TiO(2)electrode and LUMO energy level of photosensitizers. The conduction band of TiO(2)electrode could be reduced by adding the Li(+)ion in the electrolyte, attributing for the enlargement of PCE value in the QS-DSSC.
URI
http://hdl.handle.net/YU.REPOSITORY/28219http://dx.doi.org/10.1080/15421406.2013.851543
ISSN
1542-1406
Appears in Collections:
중앙도서관 > rims journal
공과대학 > 화학공학부 > Articles
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