Sonochemical Synthesis and Characterization of the New Micro-Hexagonal-Rod Lead (II)-Azido Coordination Compound

Title
Sonochemical Synthesis and Characterization of the New Micro-Hexagonal-Rod Lead (II)-Azido Coordination Compound
Author(s)
주상우요네스피로즈살라리Babak Mirtamizdoust[Babak Mirtamizdoust]
Keywords
CRYSTAL-STRUCTURE; ANTIFERROMAGNETIC INTERACTIONS; MAGNETIC-PROPERTIES; COPPER(II) COMPLEX; METAL-COMPLEXES; AZIDO BRIDGES; X-RAY; POLYMER; LIGAND; REFINEMENT
Issue Date
201207
Publisher
SPRINGER
Citation
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, v.22, no.4, pp.916 - 922
Abstract
The preparation of micro hexagonal-rods of a new 1D polymeric lead(II) complex containing the Pb-2-(mu-N-3)(2) motif, [Pb(dmp)(N-3)(2)] (n) (dmp is the abbreviation of 2,9-dimethyl-1,10-phenanthroline) by the sonochemical method is described. The new microcrystal is characterized by scanning electron microscopy, X-ray diffraction (XRD), elemental analyses and infrared spectroscopy. A single crystalline material is obtained by applying a heat gradient applied to a solution of the reagents. The single-crystal XRD analyses show that the coordination number for the Pb(II) ions is six, PbN6, with "stereo-chemically active" electron lone pairs and the coordination sphere being hemidirected. The single-crystal X-ray data show the chains of [Pb(dmp)(N-3)(2)] (n) interact with each other through the pi-pi stacking interactions, which create a 3D framework.
URI
http://hdl.handle.net/YU.REPOSITORY/27695http://dx.doi.org/10.1007/s10904-012-9681-0
ISSN
1574-1443
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공과대학 > 기계공학부 > Articles
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