Synthesis and structural characterization of three dinuclear Copper(II) complexes incorporating pyrazolyl-derived ligands

Title
Synthesis and structural characterization of three dinuclear Copper(II) complexes incorporating pyrazolyl-derived ligands
Author(s)
주상우요네스피로즈살라리Behzad Soltani[Behzad Soltani]Moayad Hossaini Sadr[Moayad Hossaini Sadr]James T. Engle[James T. Engle]Christopher J. Ziegler[Christopher J. Ziegler]
Keywords
TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; CHEMISTRY; SILVER(I); CU(I)
Issue Date
201208
Publisher
SPRINGER
Citation
TRANSITION METAL CHEMISTRY, v.37, no.8, pp.687 - 694
Abstract
Three new binuclear copper complexes of formulae (1), (2) and (3) (Pz(Me3) = 3,4,5-trimethylpyrazole, Pz(Ph2Me) = 4-methyl-3,5-diphenylpyrazole and Pz(PhMe) = 3-methyl-5-phenylpyrazole) have been synthesized and characterized by chemical analysis, FTIR and P-31 NMR spectroscopy and single-crystal X-ray diffraction. Complex 1 is a doubly bromo-bridged dimer, while complexes 2 and 3 are chloro-bridged dimers. The Cu(II) centers are in a distorted tetrahedral geometry for 1 and 2 and a distorted square pyramidal N2Cl3 environment for 3.
URI
http://hdl.handle.net/YU.REPOSITORY/27541http://dx.doi.org/10.1007/s11243-012-9639-7
ISSN
0340-4285
Appears in Collections:
공과대학 > 기계공학부 > Articles
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