PPM amount of Fe(III)-mediated ATRP of MMA with phosphorus-containing ligands in the absence of any additives
- PPM amount of Fe(III)-mediated ATRP of MMA with phosphorus-containing ligands in the absence of any additives
- 노석균; 진상웅; 한모드유스프
- TRANSFER RADICAL POLYMERIZATION; MEDIATED ICAR ATRP; METHYL-METHACRYLATE; ELECTRON-TRANSFER; ARGET ATRP; CATALYST CONCENTRATION; BLOCK-COPOLYMERS; IRON CATALYSTS; AGET ATRP; COMPLEX
- Issue Date
- ROYAL SOC CHEMISTRY
- POLYMER CHEMISTRY, v.3, no.8, pp.1971 - 1974
- MMA was polymerized via new oxidation-free ATRP by using ppm amounts of a Fe(III)-mediated ATRP system with four phosphorus containing ligands without any external reducing agent or free radical initiator. Well-controlled polymerizations were able to be achieved to produce PMMA with a high molecular weight (>300 000) and low polydispersity (PDI < 1.3) with a 10 ppm amount of FeBr3.
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