PPM amount of Fe(III)-mediated ATRP of MMA with phosphorus-containing ligands in the absence of any additives

Title
PPM amount of Fe(III)-mediated ATRP of MMA with phosphorus-containing ligands in the absence of any additives
Author(s)
노석균진상웅한모드유스프
Keywords
TRANSFER RADICAL POLYMERIZATION; MEDIATED ICAR ATRP; METHYL-METHACRYLATE; ELECTRON-TRANSFER; ARGET ATRP; CATALYST CONCENTRATION; BLOCK-COPOLYMERS; IRON CATALYSTS; AGET ATRP; COMPLEX
Issue Date
201208
Publisher
ROYAL SOC CHEMISTRY
Citation
POLYMER CHEMISTRY, v.3, no.8, pp.1971 - 1974
Abstract
MMA was polymerized via new oxidation-free ATRP by using ppm amounts of a Fe(III)-mediated ATRP system with four phosphorus containing ligands without any external reducing agent or free radical initiator. Well-controlled polymerizations were able to be achieved to produce PMMA with a high molecular weight (>300 000) and low polydispersity (PDI < 1.3) with a 10 ppm amount of FeBr3.
URI
http://hdl.handle.net/YU.REPOSITORY/27505http://dx.doi.org/10.1039/c2py20182h
ISSN
1759-9954
Appears in Collections:
총장실 > 총장실 > Articles
공과대학 > 화학공학부 > Articles
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