Sonochemical Synthesis and Characterization of A Nano-Rod Lead(II) Supramolecular, Three Dimensional Coordination Compound: New Precursor to Produce Pure Phase Nano-Sized Lead(II) Oxide

Title
Sonochemical Synthesis and Characterization of A Nano-Rod Lead(II) Supramolecular, Three Dimensional Coordination Compound: New Precursor to Produce Pure Phase Nano-Sized Lead(II) Oxide
Author(s)
주상우요네스피로즈살라리Babak Mirtamizdoust[Babak Mirtamizdoust]
Keywords
LONE-PAIR; NANOSTRUCTURES; COMPLEXES
Issue Date
201209
Publisher
SPRINGER
Citation
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, v.22, no.5, pp.952 - 956
Abstract
Nanorods of a lead(II) supramolecular three-dimensional (3D) coordination compound, [Pb(tfpb)(2)](n) (1) (Htfpb = 4,4,4-trifluoro-1-phenyl-1,3-butanedione), was prepared by the sonochemical method. The new nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction, elemental analyses and IR spectroscopy. A single-crystal structure of the compound showed that the coordination number of Pb(II) is eight with six O-donor atoms from the tfpb ligand and two F-donors from anionic ligands. The 3D supramolecular structure of 1 is realized by weak directional C-F center dot center dot center dot F-C and pi-pi stacking interactions. After calcination of nano-sized 1 at 500 A degrees C, pure phase nano-sized lead(II) oxide is produced.
URI
http://hdl.handle.net/YU.REPOSITORY/27356http://dx.doi.org/10.1007/s10904-012-9678-8
ISSN
1574-1443
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공과대학 > 기계공학부 > Articles
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