Hydrothermal Synthesis of a Nano-sized Mercury(II) N-N-O Donor Coordination Compound

Title
Hydrothermal Synthesis of a Nano-sized Mercury(II) N-N-O Donor Coordination Compound
Author(s)
주상우요네스피로즈살라리Samaneh Khanalilou[Samaneh Khanalilou]Elham Paknahad[Elham Paknahad]Moayad Hossaini Sadr[Moayad Hossaini Sadr]Behzad Soltani[Behzad Soltani]
Keywords
SCHIFF-BASE LIGANDS; ANTIMICROBIAL ACTIVITIES; SEMICARBAZONE LIGANDS; STRUCTURAL-CHARACTERIZATION; ZINC(II) COMPLEXES; CRYSTAL-STRUCTURES; METAL-COMPLEXES; POLYMERS; THIOSEMICARBAZONE; ARCHITECTURES
Issue Date
201211
Publisher
SPRINGER
Citation
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, v.22, no.6, pp.1248 - 1253
Abstract
A novel nano-structures mercury(II) coordination compound, [Hg (HPCIH) I-2] (1), ("HPCIH" is the abbreviation of 2-pyridinecarbaldehyde isonicotinoyl hydrazone) has been synthesized by a hydrothermal method that produces the coordination compound at nano size. The new nanostructure was characterized by transmission electron microscopy, scanning electron microscopy, X-ray powder diffraction elemental analysis and IR spectroscopy. Compound 1 was structurally characterized by single crystal X-ray diffraction and the single-crystal structure of this complex shows that each mercury(II) center is five coordinated with two N-donor and one O-donor atoms from "HPCIH" ligand and two iodo anions. Self-assembly of this complexes is realized by CH center dot center dot center dot center dot I, I center dot center dot center dot center dot I and pi-pi stacking interactions. The supramolecular features in these complexes are controlled by weak directional intermolecular interactions.
URI
http://hdl.handle.net/YU.REPOSITORY/26979http://dx.doi.org/10.1007/s10904-012-9731-7
ISSN
1574-1443
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공과대학 > 기계공학부 > Articles
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