Sonochemical Synthesis of Nano-structured Lead(II) Coordination Polymer with 2-Aminonicotinic Acid: Thermal, Structural and X-ray Powder Diffraction Studies

Title
Sonochemical Synthesis of Nano-structured Lead(II) Coordination Polymer with 2-Aminonicotinic Acid: Thermal, Structural and X-ray Powder Diffraction Studies
Author(s)
주상우Ali Morsali[Ali Morsali]Akram Panjehpour[Akram Panjehpour]
Keywords
HYDROTHERMAL SYNTHESIS; NANOSTRUCTURES; PRECURSORS; OXIDE; CATALYSTS; FILMS
Issue Date
201211
Publisher
SPRINGER
Citation
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, v.22, no.6, pp.1341 - 1349
Abstract
A new one-dimensional crystalline and nano-structured Pb(II) coordination polymer, [Pb(2-anc)(2)(NO3)(2)] (n) (1) {2-Hanc = 2-aminonicotinic acid}, were synthesized via heat gradient and sonochemical methods. The new produced nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy, and elemental analyses. Structural characterization by single crystal X-ray diffraction exhibits two-dimensional polymeric units for compound 1. Thermal stability of nano and bulk samples of compound 1 were studied and compared. PbO nano-particles was then obtained via calcination of nano-compound 1 at high and low temperatures. The calcinations result demonstrates that compound 1 may be suitable precursor for the preparation of nanoscale lead(II) oxide without need for special conditions like high temperature, long times and pressure control.
URI
http://hdl.handle.net/YU.REPOSITORY/26978http://dx.doi.org/10.1007/s10904-012-9771-z
ISSN
1574-1443
Appears in Collections:
공과대학 > 기계공학부 > Articles
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