Solvothermal Synthesis of a Nano-sized Aza-aromatic Base Adduct of a Cadmium(II) 4,4-Difluoro-1-phenyl-1,3-butandionate Coordination Compound

Title
Solvothermal Synthesis of a Nano-sized Aza-aromatic Base Adduct of a Cadmium(II) 4,4-Difluoro-1-phenyl-1,3-butandionate Coordination Compound
Author(s)
주상우요네스피로즈살라리Elham Paknahad[Elham Paknahad]Babak Mirtamizdoust[Babak Mirtamizdoust]
Keywords
COMPLEXES; ANION; NANOSTRUCTURES; PYRIDINE; LIGAND; UNITS; ACID
Issue Date
201211
Publisher
SPRINGER
Citation
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, v.22, no.6, pp.1365 - 1369
Abstract
A new nano-structured cadmium(II) coordination compound, [Cd(phen)(dfpb)(2)] (1) (phen = 1,10-phenanthroline, dfpb = 4,4-difluoro-1-phenyl-1,3-butandion), was synthesized by a solvothermal method and produced a coordination polymer in the nano-size range. The new nanostructure was characterized by scanning electron microscopy, X-ray powder diffraction elemental analysis and IR spectroscopy. Compound 1 was structurally characterised by single crystal X-ray diffraction. The single crystal structure shows a coordination number for the Cd ion of six with two N-donor atoms from the phen ligand and four O-donors from the two dfpb moieties. Self-assembly occurs by CH center dot center dot center dot center dot F-C and pi-pi stacking interactions. The supramolecular features in these complexes are controlled by weak directional intermolecular interactions.
URI
http://hdl.handle.net/YU.REPOSITORY/26974http://dx.doi.org/10.1007/s10904-012-9736-2
ISSN
1574-1443
Appears in Collections:
공과대학 > 기계공학부 > Articles
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