Efficient and Facile Synthesis of alpha-Chloroenones Bearing beta-Carbonates or beta-Carbamates

Title
Efficient and Facile Synthesis of alpha-Chloroenones Bearing beta-Carbonates or beta-Carbamates
Author(s)
이용록소마이마가크리쉬나
Keywords
CYCLIC DIAZODICARBONYL COMPOUNDS; RHODIUM(II)-CATALYZED REACTIONS; CATALYZED-REACTIONS; DIAZO-COMPOUNDS; ENONES; CYCLOADDITION; HALOENONES; IODOENONES; MECHANISM; HALIDES
Issue Date
201212
Publisher
KOREAN CHEMICAL SOC
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.33, no.12, pp.4150 - 4154
Abstract
Efficient synthesis of alpha-chloroenones bearing beta-carbonates or beta-carbamates was achieved by rhodium(II)-catalyzed reaction of cyclic diazodicarbonyl compounds with a variety of chloroformates or carbamyl chlorides in good yields. These reactions provided a useful and rapid route to beta-substituted alpha-haloenones.
URI
http://hdl.handle.net/YU.REPOSITORY/26698http://dx.doi.org/10.5012/bkcs.2012.33.12.4150
ISSN
0253-2964
Appears in Collections:
공과대학 > 화학공학부 > Articles
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