Photochemical Approach to the Preparation of Lariat Crown Ethers Containing Peptide Sidearms

Title
Photochemical Approach to the Preparation of Lariat Crown Ethers Containing Peptide Sidearms
Author(s)
조대원Chunsheng Quan[Chunsheng Quan]박혜정[박혜정]윤웅찬[윤웅찬]Patrick S. Mariano[Patrick S. Mariano]
Keywords
POLYDONOR-SUBSTITUTED PHTHALIMIDES; CATION-BINDING; CHIRAL RECOGNITION; ELECTRON-TRANSFER; PHOTOCYCLIZATION REACTIONS; FLUORESCENCE; PHOTOREACTIONS; SENSORS; IONS
Issue Date
201102
Publisher
KOREAN CHEMICAL SOC
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.32, no.2, pp.503 - 509
Abstract
New types of lariat type crown ethers containing peptide sidearms were prepared by using a novel strategy employing single electron transfer (SET)-induced photocyclization reactions of alpha-silylether terminated phthalimides. Reactions of chiral substrates in this series produced diastereomeric mixtures of crown ether products as a result of the formation of new stereogenic center generation in the photocyclization process.
URI
http://hdl.handle.net/YU.REPOSITORY/25655http://dx.doi.org/10.5012/bkcs.2011.32.2.503
ISSN
0253-2964
Appears in Collections:
이과대학 > 화학생화학부 > Articles
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