Synthesis and properties of an ionic polyacetylene by the activated polymerization of 2-ethynylpyridine with the ring-opening of propiolactone

Title
Synthesis and properties of an ionic polyacetylene by the activated polymerization of 2-ethynylpyridine with the ring-opening of propiolactone
Author(s)
류원석제갈영순[제갈영순]진성호[진성호]박영일[박영일]박종욱[박종욱]임권택[임권택]
Keywords
SOLAR-CELL APPLICATIONS; FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; CONJUGATED POLYMER; METATHESIS POLYMERIZATION; ELECTRICAL-CONDUCTIVITY; ORGANIC POLYMERS; CLICK POLYMERS; NOBEL LECTURE; CYCLOPOLYMERIZATION
Issue Date
201103
Publisher
ELSEVIER SCIENCE SA
Citation
SYNTHETIC METALS, v.161, no.5-6, pp.445 - 449
Abstract
A new ionic polyacetylene was prepared by the activated polymerization of 2-ethynylpyridine with the ring-opening of beta-propiolactone without any additional initiator or catalyst. The polymerization proceed well in homogeneous manner even at the mild reaction conditions to give a high yield of polymer (86%). The chemical structure of polymer was characterized by various instrumental methods to have polyacetylene polymer backbone with (N-propionate)pyridium substituents. This zwitterionic polymer was soluble in such polar protic solvents as water, methanol, DMF, DMSO, N,N-dimethylacetamide, or organic acids capable of hydrogen bonding with the propionate anion. The electrical conductivity of iodine-doped ionic polyacetylene was 3.4 x 10(-3) S/cm. The photoluminescence spectrum of polymer showed that the PL peak is located at 490 nm corresponding to the photon energy of 2.53 eV. The cyclovoltammograms of polymer exhibited the irreversible electrochemical behaviors between the oxidation and reduction peaks. The oxidation current density of polymer versus the scan rates is approximately linear relationship in the range of 30-120 mV/s. It was found that the kinetics of the redox process of polymer is almost controlled by the reactant diffusion process from the oxidation current density of polymer versus the scan rates. (C) 2011 Elsevier B.V. All rights reserved.
URI
http://hdl.handle.net/YU.REPOSITORY/25553http://dx.doi.org/10.1016/j.synthmet.2010.12.026
ISSN
0379-6779
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섬유패션학부 > 섬유패션학부 > Articles
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