New synthetic route to N-tocopherol derivatives: synthesis of pyrrolopyridinol analogue of alpha-tocopherol from pyridoxine

Title
New synthetic route to N-tocopherol derivatives: synthesis of pyrrolopyridinol analogue of alpha-tocopherol from pyridoxine
Author(s)
남태규[남태규]구진모[구진모]박형근[박형근]Ned A. Porter[Ned A. Porter]정병선
Keywords
CHAIN-BREAKING ANTIOXIDANTS; PHASE-TRANSFER CATALYSTS; 6-AMINO-3-PYRIDINOLS; 5-PYRIMIDINOLS; REACTIVITY
Issue Date
201103
Publisher
ROYAL SOC CHEMISTRY
Citation
ORGANIC & BIOMOLECULAR CHEMISTRY, v.9, no.6, pp.1749 - 1755
Abstract
A new synthetic route to pyrrolopyridinol antioxidants from easily accessible pyridoxine was developed which includes phase-transfer catalytic alkylation and intramolecular Cu(I)-catalyzed amination as key steps.
URI
http://hdl.handle.net/YU.REPOSITORY/25543http://dx.doi.org/10.1039/c0ob00991a
ISSN
1477-0520
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약학대학 > 약학부 > Articles
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