Total Synthesis of Chiricanine A, Arahypin-1, trans-Arachidin-2, trans-Arachidin-3, and Arahypin-5 from Peanut Seeds
- Title
- Total Synthesis of Chiricanine A, Arahypin-1, trans-Arachidin-2, trans-Arachidin-3, and Arahypin-5 from Peanut Seeds
- Author(s)
- 이용록; 박병호[박병호]; 이희진[이희진]
- Keywords
- 1ST TOTAL-SYNTHESIS; PHYTOALEXIN PRODUCTION; RESVERATROL OLIGOMERS; ANTIOXIDANT ACTIVITY; STILBENE; OLIGOSTILBENES; CANCER; INTERRELATIONSHIP; PICEATANNOL; PREVENTION
- Issue Date
- 201104
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF NATURAL PRODUCTS, v.74, no.4, pp.644 - 649
- Abstract
- The first and efficient syntheses of the naturally occurring prenylated stilbenes chiricanine A (2), arahypin-1 (3), trans-arachidin-2 (4),trans-arachidin-3 (5), and arahypin-5 (6) are described. Syntheses of 2 and 3 were accomplished by either a convergent sequence or a one-step reaction starting from pinosylvin. Syntheses:of 4, 5, and 6 were achieved from (E)-3,5-bis-methoxymethyl-4'-triisopropylsilyloxystilbene obtained by a Honer-Wadsworth-Emmons reaction between a benzaldehyde possessing bis-methoxymethyl ether groups and a benzyl phosphonate with a triisopropylsilyloxy group.
- URI
- http://hdl.handle.net/YU.REPOSITORY/25355http://dx.doi.org/10.1021/np100696f
- ISSN
- 0163-3864
- Appears in Collections:
- 공과대학 > 화학공학부 > Articles
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