Thirty Six Years of Research on the Selective Reduction and Hydroboration

Title
Thirty Six Years of Research on the Selective Reduction and Hydroboration
Author(s)
차진순
Keywords
REPRESENTATIVE FUNCTIONAL-GROUPS; STEREOSELECTIVE REDUCING AGENT; LITHIUM TRIS(DIETHYLAMINO)ALUMINUM HYDRIDE; MEERWEIN-PONNDORF-VERLEY; CARBOXYLIC-ACID SALTS; ALKALI-METAL HYDRIDES; THEXYLCHLOROBORANE-METHYL SULFIDE; EXCEPTIONALLY FACILE REDUCTION; ALKYL-SUBSTITUTED EPOXIDES; THEXYLBROMOBORANE-DIMETHYL SULFIDE
Issue Date
201106
Publisher
KOREAN CHEMICAL SOC
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.32, no.6, pp.1808 - 1846
Abstract
From 1975 to 2011, for thirty six years, the author and his collaborators have developed a variety of reducing and hydroborating agents, and applied them to organic synthesis, which involves the 1,2-reduction of alpha,beta-unsaturated carbonyl compounds, stereoselective reduction of cycloalkanones, regioselective ring-opening of epoxides, partial reduction of carboxylic acid derivatives to aldehydes, regioselective addition to carbon-carbon multiple bonds, etc. by utilizing metal hydrides and the newly-devised the Meerwein-Ponndorf-Verley (MPV) type reagents. Such developments provide a new synthetic methodology making possible valuable selective reductions and hydroborations, not practical previously.
URI
http://hdl.handle.net/YU.REPOSITORY/25091http://dx.doi.org/10.5012/bkcs.2011.32.6.1808
ISSN
0253-2964
Appears in Collections:
문과대학 > 중국언어문화학과 > Articles
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