A Concise, metathesis based approach to construction of the lepadiformine/cylindricine tricyclic framework

Title
A Concise, metathesis based approach to construction of the lepadiformine/cylindricine tricyclic framework
Author(s)
조대원Jiwen Zou[Jiwen Zou]Patrick S. Mariano[Patrick S. Mariano]
Keywords
RING-CLOSING METATHESIS; NITROGEN-CONTAINING HETEROCYCLES; CLAVELINA-LEPADIFORMIS MULLER; DIENYNE METATHESIS; MARINE ALKALOIDS; AMINO-ACIDS
Issue Date
201008
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
TETRAHEDRON, v.66, no.32, pp.5955 - 5961
Abstract
A tandem dienyne metathesis based strategy has been developed for construction of the core tricyclic framework found in the lepadiformine and cylindricine alkaloids. 2-Pentenyl-2-ethynylpyrollidine acrylamide that serves as the starting material for the key ruthenium carbene catalyzed metathesis process is prepared by using a concise route starting with L-proline. (c) 2010 Elsevier Ltd. All rights reserved.
URI
http://hdl.handle.net/YU.REPOSITORY/23834http://dx.doi.org/10.1016/j.tet.2010.06.027
ISSN
0040-4020
Appears in Collections:
이과대학 > 화학생화학부 > Articles
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