New Synthetic Routes to Biologically Interesting Geranylated Acetophenones from Melicope Semecarpifolia and Their Unnatural Prenylated and Farnesylated Derivatives

Title
New Synthetic Routes to Biologically Interesting Geranylated Acetophenones from Melicope Semecarpifolia and Their Unnatural Prenylated and Farnesylated Derivatives
Author(s)
이용록하립개[하립개]만찰라 나라시물루[만찰라 나라시물루]이신[이신]심재진
Keywords
ANTIPLATELET AGGREGATION CONSTITUENTS; PYRANOCHALCONE NATURAL-PRODUCTS; CONCISE TOTAL-SYNTHESIS; ALPHA,BETA-UNSATURATED ALDEHYDES; QUINOLINE ALKALOIDS; EFFICIENT SYNTHESIS; MALLOTOPHILIPPEN-C; ORIXALONE-D; FRUITS; FLAVONOIDS
Issue Date
201003
Publisher
KOREAN CHEMICAL SOC
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.31, no.3, pp.664 - 669
Abstract
This paper describes a new synthetic approach for biologically interesting geranylated acetophenones. The first total syntheses of 1-(5-geranyloxy-7-hydroxy-2,2-dimethyl-2H-chromen-8-yl)ethanone and 1-[5-geranyloxy-7-hydroxy-2-methyl-2-(4-methylpent-3-enyl)-2H-chromen-8-yl]ethanone, isolated from Melicope semecarpifolia, were carried out starting from commercially available 2,4,6-trihydroxyacetophenone.
URI
http://hdl.handle.net/YU.REPOSITORY/22788http://dx.doi.org/10.5012/bkcs.2010.31.03.664
ISSN
0253-2964
Appears in Collections:
공과대학 > 화학공학부 > Articles
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